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A tetrel bond was characterized in the complexes of 1,4-diazabicyclo[2.2.2]octane (DABCO) with TH 3 X (T = C, Si, Ge; X= –Me, –H, –OH, –NH 2 , –F, –Cl, –Br, –I, –CN, –NO 2 ).

Systematic study of the substitution effect on the tetrel bond between 1,4-diazabicyclo[2.2.2]octane and TH3X

Systematic study of the substitution effect on the tetrel bond between 1,4-diazabicyclo[2.2.2]octane and TH₃X