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K. Wang and X. Song contributed equally to this work. Prof. G. Li thanks for the general supported by the National Key RD Prof A. K. Kyaw thanks for general support by Thousand Talents Program of China and Shenzhen Municipal Science and Technology Innovation Committee and Shenzhen Peacock Team Project (No. KQTD2016030111203005). Prof. D. Baran thanks for the general supported by KAUST Solar Center Competitive Fund (CCF) for financial support.

Efficient as-cast thick film small-molecule organic solar cell with less fluorination on the donor