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Generally, hybrid white organic light-emitting diodes (WOLEDs) are constructed with blue fluorophores and yellow or green/red phosphors, and the fluorophores and phosphors used have to be doped into proper hosts to avoid the exciton quenching caused by molecular aggregation, which brings difficulties in device structure design and fabrication. In this paper, we fabricated high efficiency/low efficiency roll-off/high CRI hybrid WOLEDs based on aggregation-induced emission (AIE) luminogens (AIEgens) with non-doping features as the fluorophore emitters. The resulting WOLEDs were constructed by two AIEgens that emit blue and green light, respectively, and a doped red phosphor, greatly simplifying the device structure. Encouragingly, the hybrid WOLEDs simultaneously achieved high efficiency (PEmax = 50.5 lm W−1, EQEmax = 20.5%), low efficiency roll-off (PE1000nit = 32.9 lm W−1, EQE1000nit = 18.9%), and high CRI (≥90). Our results indicate that AIEgens are promising material systems for manufacturing high-performance white OLEDs with a simple device structure.

materials chemistry frontiers

Design and performance study of high efficiency/low efficiency roll-off/high CRI hybrid WOLEDs based on aggregation-induced emission materials as fluorescent emitters