English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

In this study, the synthesis of [2]rotaxanes as fluorescent metal ion sensors has been demonstrated. [2]Rotaxanes, RA-H·PF6, RRA and RRB, undergo photoelectron transfer resulting in fluorescence quenching. Before the diimine (dynamic covalent bond) reduction on the macrocyclic ring, the dynamic [2]rotaxane RA-H·PF6 can be hydrolyzed and turned fluorescent by trivalent metal ions, giving fluorescence at λmax 424 nm. After reduction of the imines, the reduced [2]rotaxanes RRA and RRB are kinetically stable and highly selective to Au3+ binding among 27 metal ions in a water-compatible (50 vol%) solution with working fluorescence in the range of pH 4–10. 50-Fold and 1.2-fold fluorescence turn-on after addition of Au3+ has been observed for RRA and RRB, respectively. Metal interference on Au3+ detection is insignificant, and thereby the fluorescence intensity is linearly proportional to the concentration of Au3+ until excess. The solid-state crystal structure of RRA shows the mechanically interlocked structure (mechanical bond). The bioimaging experiment of RRB with HeLa cells demonstrates the potential application of these mechanically interlocked molecules for metal ion detection in aqueous media and biological systems.

Water-compatible fluorescent [2]rotaxanes for Au3+ detection and bioimaging

Water-compatible fluorescent [2]rotaxanes for Au³⁺ detection and bioimaging