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A light-stimuli-responsive supramolecular azobenzene-containing M 2 L 4  cage has been designed and synthesized. This cage can be reversibly disassembled/reassembled mediated by the azo-ligand under visible and UV light irradiation.

materials chemistry frontiers

Light-triggered reversible disassembly of stimuli-responsive coordination metallosupramolecular Pd<sub>2</sub>L<sub>4</sub> cages mediated by azobenzene-containing ligands

Light-triggered reversible disassembly of stimuli-responsive coordination metallosupramolecular Pd2L4 cages mediated by azobenzene-containing ligands

Light-triggered reversible disassembly of stimuli-responsive coordination metallosupramolecular Pd₂L₄ cages mediated by azobenzene-containing ligands