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If we wish to sustain our terrestrial ecosphere as we know it, then reducing the concentration of atmospheric CO_2 is of critical importance. An ideal pathway for achieving this would be the use of sunlight to recycle CO_2, in combination with water, into hydrocarbon fuels compatible with our current energy infrastructure. However, while the concept is intriguing such a technology has not been viable due to the vanishingly small CO_2-to-fuel photoconversion efficiencies achieved. Herein we report a photocatalyst, reduced blue-titania sensitized with bimetallic Cu–Pt nanoparticles that generates a substantial amount of both methane and ethane by CO_2 photoreduction under artificial sunlight (AM1.5): over a 6 h period 3.0 mmol g^(−1) methane and 0.15 mmol g^(−1) ethane are obtained (on an area normalized basis 0.244 mol m^(−2) methane and 0.012 mol m^(−2) ethane), while no H_2 nor CO is detected. This activity (6 h) translates into a sustained Joule (sunlight) to Joule (fuel) photoconversion efficiency of 1%, with an apparent quantum efficiency of φ = 86%. The time-dependent photoconversion efficiency over 0.5 h intervals yields a maximum value of 3.3% (φ = 92%). Isotopic tracer experiments confirm the hydrocarbon products originate from CO_2 and water.

CO2, water, and sunlight to hydrocarbon fuels: a sustained sunlight to fuel (Joule-to-Joule) photoconversion efficiency of 1%

CO₂, water, and sunlight to hydrocarbon fuels: a sustained sunlight to fuel (Joule-to-Joule) photoconversion efficiency of 1%