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Asymmetric hydrogenation catalysis by [(μ-H) 2 Ru 3 (μ 3 -S)(CO) 7 (μ-P–P*)] (P–P* = chiral diphosphine) indicates intact chiral clusters as active catalysts.

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Asymmetric hydrogenation of an α-unsaturated carboxylic acid catalyzed by intact chiral transition metal carbonyl clusters – diastereomeric control of enantioselectivity