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Three equivalents of LGa {L = HC[C(Me)N(2,6-i-Pr 2 C 6 H 3 )] 2 } react with AsX 3 (X = Cl, Br) by insertion into two As-X bonds, followed by the elimination of LGaX 2 and formation of LGaAsGa(Cl)L (1) and LGaAsGa(Br)L (2). According to single crystal X-ray analysis, 1 and 2 each exhibit one Ga-As single bond and one Ga-As double bond. The π-bonding contribution (9.71 kcal mol -1 1 and 9.44 kcal mol -1 2) was proved by variable temperature (VT) 1 H NMR spectroscopy, while the electronic structure of 1' was studied by quantum chemical calculations.

Synthesis and structures of gallaarsenes LGaAsGa(X)L featuring a Ga–As double bond