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A trigonal planar Pb(+I)Mn 3  cluster is observed in the carbonyl compound [Pb{Mn(CO) 5 } 3 ][AlCl 4 ] that was prepared by ionic-liquid-based synthesis.

[Pb{Mn(CO)5}3][AlCl4]: a lead-manganese carbonyl with AlCl4-linked PbMn3 clusters

[Pb{Mn(CO)₅}₃][AlCl₄]: a lead-manganese carbonyl with AlCl₄-linked PbMn₃ clusters