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The direct synthesis of hydrogen peroxide is investigated using PdGa/TiO2 and PdIn/TiO2 catalysts prepared by an acid-washed sol-immobilisation procedure, which allows for good control of particle size. The introduction of both Ga and In into a supported Pd catalyst leads to significantly reduced rates of H2O2 degradation in comparison to the monometallic counterpart. Detailed characterisation reveals that this enhancement is a result of selectively tuning the ratio of Pd oxidation states.

The direct synthesis of hydrogen peroxide from H2 and O2 using Pd–Ga and Pd–In catalysts

The direct synthesis of hydrogen peroxide from H₂ and O₂ using Pd–Ga and Pd–In catalysts