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Di-anions of manganocene derivatives complexes, in spite of being a 19-electron system, are found to be more stable than their mono-anions. This defiance of the 18-electron rule is linked to the geometrical distortion of the di-anion, akin to the Jahn-Teller-like mechanism.

Ligand stabilization of manganocene dianions – in defiance of the 18-electron rule