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Reinvestigation of the assembly of bis((pyrrol-2-yl)methylene)hydrazine with Ag(I) salts suggests that, in the solid state, Ag–π interactions involve CC rather than CN pyrrolic bonds, in contrast with an earlier and unique report with this ligand.

Revisiting Ag–π interactions with bis((pyrrol-2-yl)methylene)hydrazine: CC versus CN bond complexation