English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Herein we report the transformation of [Au 25 (SR) 18 ] 0 into Au 28 (SR) 21 induced by ligand exchange reaction. In contrast to other reported cluster transformations, which proceed at elevated temperature and large excess of incoming ligands, the transformation reported here occurs under mild conditions (room temperature, very low thiol excess) with a chiral ligand. A difference of one methyl group between incoming and leaving thiol is sufficient to induce the transformation. To the best of our knowledge the Au 28 (SR) 21 cluster has not been isolated before.

chemical communications

Transformation from [Au25(SCH2CH2CH2CH3)18]0 to Au28(SCH2CH(CH3)Ph)21 gold nanoclusters: gentle conditions is enough