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Heavy metal-free CuInS 2 quantum dots (QDs) were employed as a photosensitizer on a NiO photocathode to drive an immobilized molecular Re catalyst for photoelectrochemical CO 2 reduction for the first time. A photocurrent of 25 μA cm -2 at -0.87 V vs. NHE was obtained, providing a faradaic efficiency of 32% for CO production.

chemical communications

A heavy metal-free CuInS<sub>2</sub> quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO<sub>2</sub> reduction

A heavy metal-free CuInS2 quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO2 reduction

A heavy metal-free CuInS₂ quantum dot sensitized NiO photocathode with a Re molecular catalyst for photoelectrochemical CO₂ reduction