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The [Mn 2 Cl 9 ] 5- mode of red emissive (C 4 NOH 10 ) 5 Mn 2 Cl 9 ·C 2 H 5 OH under thermal treatment will be cleaved into [MnCl 4 ] 2- in the green emissive (C 4 NOH 10 ) 2 MnCl 4 with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.

Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals