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Using transition metal ions for spin-based applications, such as electron paramagnetic resonance imaging (EPRI) or quantum computation, requires a clear understanding of how local chemistry influences spin properties. Herein we report a series of four ionic complexes to provide the first systematic study of one aspect of local chemistry on the V(iv) spin - the counterion. To do so, the four complexes (Et 3 NH) 2 [V(C 6 H 4 O 2 ) 3 ] ( 1 ), ( n -Bu 3 NH) 2 [V(C 6 H 4 O 2 ) 3 ] ( 2 ), ( n -Hex 3 NH) 2 [V(C 6 H 4 O 2 ) 3 ] ( 3 ), and ( n -Oct 3 NH) 2 [V(C 6 H 4 O 2 ) 3 ] ( 4 ) were probed by EPR spectroscopy in solid state and solution. Room temperature, solution X-band ( ca. 9.8 GHz) continuous-wave electron paramagnetic resonance (CW-EPR) spectroscopy revealed an increasing linewidth with larger cations, likely a counterion-controlled tumbling in solution via ion pairing. In the solid state, variable-temperature (5-180 K) X-band ( ca. 9.4 GHz) pulsed EPR studies of 1-4 in o -terphenyl glass demonstrated no effect on spin-lattice relaxation times ( T  1 ), indicating little role for the counterion on this parameter. However, the phase memory time ( T  m ) of 1 below 100 K is markedly smaller than those of 2-4 . This result is counterintuitive, as 2-4 are relatively richer in 1 H nuclear spin, hence, expected to have shorter T  m . Thus, these data suggest an important role for counterion methyl groups on T  m , and moreover provide the first instance of a lengthening T  m with increasing nuclear spin quantity on a molecule.

Counterion influence on dynamic spin properties in a V(iv) complex