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The trans -tetrafluoro-λ 6 -sulfane (SF 4 ) group has been utilized as a unique three-dimensional building block for the linear connection of two independent N-heterocycles, pyridines and triazoles. The linearly connected heterocyclic compounds were synthesized by thermal Huisgen 1,3-dipolar cycloaddition between previously unknown pyridine SF 4 -alkynes and readily available azides, providing a series of rod-like SF 4 -connected N-heterocycles in good to excellent yields. X-ray crystallographic analysis of the target products revealed the trans -geometry of the SF 4 group, which linearly connects two independent N-heterocycles. This research will open the field of chemistry of SF 4 -connected heterocyclic compounds.

An eccentric rod-like linear connection of two heterocycles: synthesis of pyridine trans-tetrafluoro-λ6-sulfanyl triazoles

An eccentric rod-like linear connection of two heterocycles: synthesis of pyridine trans-tetrafluoro-λ⁶-sulfanyl triazoles