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To understand the dynamics of the cation in layered perovskite-type (CH 3 CH 2 NH 3 ) 2 CuCl 4 , the temperature-dependent chemical shifts and spin–lattice relaxation times  T  1ρ  have been measured using  1 H MAS NMR and  13 C CP/MAS NMR techniques.

rsc advances

Cation dynamics by 1H and 13C MAS NMR in hybrid organic–inorganic (CH3CH2NH3)2CuCl4