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A new method was developed to synthesize N 2 -alkyl-substituted 1,2,3-triazoles via gold catalyzed alkylation of vinyl ethers with mono- and unsubstituted NH-1,2,3-triazoles and benzotriazole. A hydrogen bond between the oxygen atom of the vinyl ethers, activated via the gold catalyst, and the NH-1,2,3-triazoles was supposed to be generated, which selectively gave the N 2 -alkylation products.

N2-selective alkylation of NH-1,2,3-triazoles with vinyl ethers via gold catalysis

N²-selective alkylation of NH-1,2,3-triazoles with vinyl ethers via gold catalysis