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Unexpected nitro-group reduced ruthenoles and 1,2-CO-inserted π-coordinated triruthenium clusters were isolated during the reactions of Ru 3 (CO) 12  with ferrocene-containing 1,3-ynones.

Reaction of FcCCC(O)R (Fc = ferrocenyl) with Ru3(CO)12 leading to unexpected nitro-group reduced ruthenoles and 1,2-CO-inserted triruthenium clusters