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This paper describes the synthesis of a triazole based bisphosphine and its transition metal chemistry and catalytic utility in Cu-free Sonogashira alkynylation/cyclization reaction.

rsc advances

1,2,3-Triazole based bisphosphine, 5-(diphenylphosphanyl)-1-(2-(diphenylphosphanyl)-phenyl)-4-phenyl-1<i>H</i>-1,2,3-triazole: an ambidentate ligand with switchable coordination modes

1,2,3-Triazole based bisphosphine, 5-(diphenylphosphanyl)-1-(2-(diphenylphosphanyl)-phenyl)-4-phenyl-1H-1,2,3-triazole: an ambidentate ligand with switchable coordination modes