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Lithium-ion cells are currently very promising electrochemical power sources. New high-capacity electrodes made from silicon are currently under intensive study. As well as its high capacity, silicon undergoes a significant volume increase (up to 300%) during lithiation. This leads to the generation of internal stresses and fast cell degradation due to active material pulverization and separation from the current collector. Stress formation and its effect on silicon lithiation has been theoretically investigated by many researchers. It has been shown that internal compressive stress can slow down or stop silicon lithiation. In our study we applied external stress to an electrode active layer and measured the cell electrochemical parameters: capacity, cycle life, and charge transfer resistance. In contrast with theoretical estimations we observed an increase in capacity and cycle life when high compressive stress was applied. We believe this behavior is related to stress-induced lithiation front slowdown, which entails a longer stress relaxation period and as a consequence improves the cell parameters.

The effect of compressive stresses on a silicon electrode’s cycle life in a Li-ion battery