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The ionic dynamics of (CH 3 NH 3 ) 2 MCl 4 (M = Cu, Zn) by 1 H MAS NMR, 13 C CP MAS NMR, and 14 N NMR are investigated as a function of temperature with a focus on the role of the CH 3 NH 3  + cation.

rsc advances

Ionic dynamics of the cation in organic–inorganic hybrid compound (CH3NH3)2MCl4(M = Cu and Zn) by1H MAS NMR,13C CP MAS NMR, and14N NMR