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Highly efficient solar absorption is very promising for many practical applications, such as power generation, desalination, wastewater treatment and steam generation. Nevertheless, so far, near-ideal solar thermal energy conversion is still difficult to achieve, which requires a near-perfect absorption from the UV to the near-infrared region and meanwhile a mid-and-far infrared absorption close to zero. Here, by employing FEM and FDTD methods respectively, a nearly omnidirectional ultra-broadband efficient selective solar absorber based on a nanoporous hyperbolic metamaterial (HMM) structure is proposed and numerically demonstrated, which can achieve an extremely high average absorption efficiency above 98.9% within the range of 260-1580 nm. More significantly, in the respect of physical mechanism, the near-perfect solar absorption of this multilayered nanostructures is primarily due to the excitation of magnetic and electric resonances resulting from localized surface plasmon resonance at metal/dielectric interfaces, working completely different from those previously reported tapered multilayered absorbers associated with the slow-light effect. Besides, for retaining heat, a low emissivity is realized in mid-infrared region, causing a near-ideal total solar-thermal conversion efficiency up to 90.32% at 373.15 K ( η  ideal = 95.6%), which is particularly useful in solar steam generation. Detailed studies are also performed for higher operating temperatures, which indicates efficient solar thermal conversions also can be well maintained by tuning geometric parameters at higher temperatures. Taking into consideration of the practical application, even with ±60 degrees angle of incidence, average absorptivity higher than 90% can be still obtained in the whole solar spectrum at both TE and TM polarization. The near-perfect absorption, wide angle, polarization independence, spectral selectivity and high tunability make this solar absorber promising for practical applications in solar energy harvesting.

rsc advances

Numerical study of a wide-angle polarization-independent ultra-broadband efficient selective metamaterial absorber for near-ideal solar thermal energy conversion