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The  1 H chemical shifts and the spin-lattice relaxation time,  T  1ρ , in the rotating frame of (NH 4 ) 2 ZnX 4  (X = Cl, Br) are observed in order to investigate local phenomena related to successive phase transitions.

rsc advances

Role of NH4 ions in successive phase transitions of perovskite type (NH4)2ZnX4 (X = Cl, Br) by 1H MAS NMR and 14N NMR