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The emission spectroscopy and photophysics reported in the title paper are shown to be untenable in light of previously reported experimental results and widely accepted theories of electronic excited state relaxation.

rsc advances

Comment on “Metal–organic green dye: chemical and physical insight into a modified Zn-benzoporphyrin for dye-sensitized solar cells” by G. Zanotti, N. Angelini, G. Mattioli, A. M. Paoletti, G. Pennesi, G. Rossi, D. Caschera, L. de Marcoc and G. Giglide, RSC Adv., 2016, 6, 5123