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Recent developments in main group chemistry towards the activation and conversion of N 2 have lead to the revelation that boron can greatly affect these processes. Boron is capable of acting both as a borane Lewis acid to activate metal-N 2 complexes and as an ambiphilic borylene able to activate free N 2 . The latter example is capable of both accepting and donating electron density in a manner reminiscent of transition metal systems containing both filled and empty d-orbitals.

Push and pull: the potential role of boron in N2 activation

Push and pull: the potential role of boron in N₂ activation