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Solvent engineering is an increasingly essential topic in the chemical sciences. In this context, some recently appeared unconventional solvents have shown their large potential in the field of C-H bond functionalization reactions. This review aims not only at recognizing and classifying a short selection of these emerging solvents, in particular halogenated ones, but also at providing a medium term perspective of the possibilities they will offer for synthetic method development.

Emerging unconventional organic solvents for C–H bond and related functionalization reactions