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Explicitly-correlated  ab initio  computations reveal novel inversion and retention pathways for several S N 2 reactions with different nucleophiles and leaving groups.

Rethinking the X− + CH3Y [X = OH, SH, CN, NH2, PH2; Y = F, Cl, Br, I] SN2 reactions

Rethinking the X⁻ + CH₃Y [X = OH, SH, CN, NH₂, PH₂; Y = F, Cl, Br, I] S_N2 reactions