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The structures of gas-phase group nine cation-nitrous oxide metal-ligand complexes, M + (N 2 O) n (M = Co, Rh, Ir; n = 2-7) have been determined by a combination of infrared photodissociation spectroscopy and density functional theory. The infrared spectra were recorded in the region of the N 2 O asymmetric (N[double bond, length as m-dash]N) stretch using the inert messenger technique and show spectroscopically distinct features for N- and O-bound isomers. The evolution of the spectra with increasing ligand number is qualitatively different for each of the metal ions studied here with only Co + (N 2 O) n complexes behaving similarly to the coinage metal complexes studied previously. The rich variety of electronic and isomeric structures identified make these species attractive targets for infrared-driven, isomer selective intra-complex chemistry.

Structural isomers and low-lying electronic states of gas-phase M+(N2O)n (M = Co, Rh, Ir) ion–molecule complexes

Structural isomers and low-lying electronic states of gas-phase M⁺(N₂O)_n (M = Co, Rh, Ir) ion–molecule complexes