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Perovskite-derived hybrid platinum iodides with the general formula A2PtIVI6 (A = formamidinium FA and guanidinium GUA) accommodate excess I2 to yield hydrogen-bond-stabilized compounds where the I2 forms catenates with I- anions on the PtI6 octahedra.

The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(iv) compounds

The capricious nature of iodine catenation in I₂ excess, perovskite-derived hybrid Pt(iv) compounds