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The selectivity of CO2 hydrogenation can be significantly tuned by controlling the valence state of nickel using lanthanum-iron-nickel perovskites. Nickel with higher valence states weakens the binding of CO and increases the activation barrier for further CO hydrogenation, leading to a higher CO selectivity than the metallic nickel.

High selectivity of CO2 hydrogenation to CO by controlling the valence state of nickel using perovskite

High selectivity of CO₂ hydrogenation to CO by controlling the valence state of nickel using perovskite