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Pincer platinum(ii) complexes are well documented to exhibit weak intermolecular interactions in the solid state and 77 K glassy solutions, leading to emissive triplet metal-metal-to-ligand charge transfer ( 3 MMLCT) excited states that often vanish in dilute solutions. In this work, metal-organic framework (MOF) materials are introduced to provide a "solid solution" environment for easy access to 3 MMLCT excited states of pincer platinum(ii) complexes. Phosphorescent composites Pt II @MOFs ( 1-4 ) with matrix-dependent monomers and oligomer emission properties were obtained. These Pt II @MOFs are efficient catalysts for photoinduced dehydrogenation reactions.

chemical science

Metal–organic framework composites with luminescent pincer platinum(<scp>ii</scp>) complexes:<sup>3</sup>MMLCT emission and photoinduced dehydrogenation catalysis

Metal–organic framework composites with luminescent pincer platinum(ii) complexes:3MMLCT emission and photoinduced dehydrogenation catalysis

Metal–organic framework composites with luminescent pincer platinum(ii) complexes:³MMLCT emission and photoinduced dehydrogenation catalysis