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Complexes exhibiting the Mo V O(μ-S)Cu I  cores, EPR properties, electronic structures and biomimetic reactions of aerobic Mo/Cu-containing carbon monoxide dehydrogenases are reported.

chemical science

Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic Mo<sup>V</sup>O(μ-S)Cu<sup>I</sup> complexes

Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic MoVO(μ-S)CuI complexes

Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic Mo^VO(μ-S)Cu^I complexes