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A highly efficient kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines  via  asymmetric Cu-catalyzed borylation has been realized for the first time to afford chiral 3-boryl-1,2,3,4-tetrahydroquinolines and recover 2-substituted 1,2-dihydroquinolines with excellent enantioselectivities and selectivity factors of up to 569.

Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylation