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Acid–base complexes prepared from sub-5 μm polyethyleneimine microballs and dicarboxylic acids promoted silica deposition to give silica microballs with different morphological surface structures which were controlled by the structures of the acids.

rsc advances

Biomimetic silica deposition promoted by sub-5 μm complexes of dicarboxylic acids/polyethyleneimine microballs: a new approach to tuning silica structures using messenger-like dicarboxylic acids