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The effect of the azide ion N 3  - on the yield of molecular hydrogen in water irradiated with 60 Co γ-rays (∼1 MeV Compton electrons) and tritium β-electrons (mean electron energy of ∼7.8 keV) at 25 °C is investigated using Monte Carlo track chemistry simulations in conjunction with available experimental data. N 3  - is shown to interfere with the formation of H 2 through its high reactivity towards hydrogen atoms and, but to a lesser extent, hydrated electrons, the two major radiolytic precursors of the H 2 yield in the diffusing radiation tracks. Chemical changes are observed in the H 2 scavengeability depending on the particular type of radiation considered. These changes can readily be explained on the basis of differences in the initial spatial distribution of primary radiolytic species ( i.e. , the structure of the electron tracks). In the "short-track" geometry of the higher "linear energy transfer" (LET) tritium β-electrons (mean LET ∼5.9 eV nm -1 ), radicals are formed locally in much higher initial concentration than in the isolated "spurs" of the energetic Compton electrons (LET ∼0.3 eV nm -1 ) generated by the cobalt-60 γ-rays. As a result, the short-track geometry favors radical-radical reactions involving hydrated electrons and hydrogen atoms, leading to a clear increase in the yield of H 2 for tritium β-electrons compared to 60 Co γ-rays. These changes in the scavengeability of H 2 in passing from tritium β-radiolysis to γ-radiolysis are in good agreement with experimental data, lending strong support to the picture of tritium β-radiolysis mainly driven by the chemical action of short tracks of high local LET. At high N 3  - concentrations (&gt;1 M), our H 2 yield results for 60 Co γ-radiolysis are also consistent with previous Monte Carlo simulations that suggested the necessity of including the capture of the precursors to the hydrated electrons ( i.e. , the short-lived "dry" electrons prior to hydration) by N 3  - . These processes tend to reduce significantly the yields of H 2 , as is observed experimentally. However, this dry electron scavenging at high azide concentrations is not seen in the higher-LET 3 H β-radiolysis, leading us to conclude that the increased amount of intra-track chemistry intervening at early time under these conditions favors the recombination of these electrons with their parent water cations at the expense of their scavenging by N 3  - .

rsc advances

Self-radiolysis of tritiated water. 4. The scavenging effect of azide ions (N3−) on the molecular hydrogen yield in the radiolysis of water by 60Co γ-rays and tritium β-particles at room temperature