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Single- and few-layer α-M 2 X 3  nanosheets exhibit out-of-plane SHG and piezoelectric properties, which can be tuned by switching spontaneous polarizations.

rsc advances

Peculiar electronic, strong in-plane and out-of-plane second harmonic generation and piezoelectric properties of atom-thick α-M<sub>2</sub>X<sub>3</sub> (M = Ga, In; X = S, Se): role of spontaneous electric dipole orientations

Peculiar electronic, strong in-plane and out-of-plane second harmonic generation and piezoelectric properties of atom-thick α-M2X3 (M = Ga, In; X = S, Se): role of spontaneous electric dipole orientations

Peculiar electronic, strong in-plane and out-of-plane second harmonic generation and piezoelectric properties of atom-thick α-M₂X₃ (M = Ga, In; X = S, Se): role of spontaneous electric dipole orientations