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A series of spinel solid solutions Li4x/3Co2−2xTi1+2x/3O4 (LCT, 0.2 ≤ x ≤ 0.8) were synthesized and their structures and microwave dielectric properties were characterized in detail. The distribution of cations at A and B sites in the lattice has been analyzed by using Rietveld refinement. The microstructure and dielectric properties were studied by scanning electron microscope and microwave network analyzer. The solid solutions undergo a discontinuous B-site, Li/Ti order–disorder phase transition from a disordered cubic phase to an ordered cubic phase with increasing x values from 0.4 to 0.6. With increasing the A-site lithium content, the LCT ceramics exhibit improved dielectric permittivity er (20.3–26.5), high Q × f value (≥29 400 GHz) and a tailored temperature coefficient of resonant frequency τf from −40 to 10 ppm per °C. Optimized microwave dielectric properties were achieved for the composition with x = 0.8: er = 26.5, Q × f ≈ 29 400 GHz and τf ≈ 10 ppm per °C. A correlation between the cation distribution and microwave dielectric loss is discussed in detail.

rsc advances

Li4x/3Co2−2xTi1+2x/3O4 spinel solid solutions: order and disorder phase transition, cations distribution and adjustable microwave dielectric properties