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The biocatalytic asymmetric Michael addition of l -arginine to fumarate using argininosuccinate lyase (ASL) has enabled the synthesis of the key metabolite l -argininosuccinic acid lithium salt 1 for the first time, with excellent yield and purity.

rsc advances

Biocatalytic asymmetric Michael addition reaction of<scp>l</scp>-arginine to fumarate for the green synthesis of N-(([(4S)-4-amino-4-carboxy-butyl]amino)iminomethyl)-<scp>l</scp>-aspartic acid lithium salt (<scp>l</scp>-argininosuccinic acid lithium salt)

Biocatalytic asymmetric Michael addition reaction ofl-arginine to fumarate for the green synthesis of N-(([(4S)-4-amino-4-carboxy-butyl]amino)iminomethyl)-l-aspartic acid lithium salt (l-argininosuccinic acid lithium salt)