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Based on the cyclization reaction of an aldehyde with an aminoalkyl thiol, a novel NIR-emitting iridium(III) complex (NIR-Ir) showed off–on phosphorescent response toward Cys and Hcy, and was developed to detect Cys/Hcy levels in vitro and in vivo.

A near-infrared phosphorescent iridium(iii) complex for imaging of cysteine and homocysteine in living cells and in vivo