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A Cd(II) coordination polymer, [Cd3(L)2(H2O)5]·(H2O)4 (1) (H3L = 9-(4-carboxy-phenyl)-9H-carbazoly-3,6-dicarboxylic acid) has been synthesized solvothermally. Compound 1 exhibits excellent luminescence and good stability in aqueous and DMF solution. In particular, 1 can detect Cu2+ ions through fluorescence quenching in aqueous solution. In addition, 1 also shows a highly sensitive response to some nitroaromatic compounds (NACs) in DMF solution. Thus, 1 can serve as a promising luminescent sensor for detecting Cu2+ ions and NACs.

A stable 3D Cd(ii) metal–organic framework for highly sensitive detection of Cu2+ions and nitroaromatic explosives

A stable 3D Cd(ii) metal–organic framework for highly sensitive detection of Cu²⁺ions and nitroaromatic explosives