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Thermal treatment of a glass with the composition 8 BaO·8 SrO·34 ZnO·50 SiO 2  has led to the crystallization of a Ba 1−x Sr x Zn 2 Si 2 O 7  solid solution at the surface.

rsc advances

Surface crystallization of low thermal expansion Ba0.5Sr0.5Zn2Si2O7 from an 8 BaO·8 SrO·34 ZnO·50 SiO2 glass