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Mannose, an underused sugar derived from hemicellulose, can be effectively converted into 5-hydroxymethylfurfural (5-HMF) with aluminum chloride catalyst under mild conditions, offering useful reference for the refinery of biomass in the future.

rsc advances

Valorization of an underused sugar derived from hemicellulose: efficient synthesis of 5-hydroxymethylfurfural from mannose with aluminum salt catalyst in dimethyl sulfoxide/water mixed solvent