English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Tools annual

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Presents the access of premium content as premium feature

Premium Content

Global: Zendy Plus annual

Global: Zendy Free Plan

Despite the proposed importance of atmospheric mercury (Hg) cycling, little is known about its heterogeneous chemistry, specifically on ubiquitous dust particle surfaces in the environment. To address this gap in knowledge, we herein report the uptake coefficients for the uptake of Hg0(g) on iron (oxyhydr)oxides (γ-Fe2O3, α-FeOOH, α-Fe2O3 and Fe3O4) nanoparticles, employed as proxies for reactive components of mineral dust. Hg0(g)-particle interactions were studied in a batch set-up, at ambient pressure (760 ± 5 Torr) and temperatures (295 ± 2 K) with UV and visible irradiation (290 nm ≤ λ ≤ 700 nm). γ-Fe2O3, α-FeOOH and α-Fe2O3 demonstrated a ca. 40–900-fold increase in uptake kinetics upon irradiation, under our experimental conditions. In contrast, uptake kinetics on Fe3O4's surface displayed little dependence on irradiation. Relative humidity was shown to inhibit the effect of radiation on the uptake of Hg0(g) by α-Fe2O3. Size distributions, electronic properties, surface area and phase characterization of the iron(oxyhydr)oxide particles were studied to explain the uptake kinetics, and to provide insights into the mechanism of Hg0(g) loss. The adsorption capacity of Hg0(g) on α-Fe2O3 was determined from the adsorption isotherm fitted with Langmuir, Freundlich and Elovich adsorption models. The implications of the results to atmospheric chemical processes are herein discussed.

Radiation enhanced uptake of Hg0(g) on iron (oxyhydr)oxide nanoparticles