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The diversity-oriented synthesis of fully substituted aniline derivatives  via  the DBU-mediated [4 + 2] annulation of donor-acceptor 1,1-dicyanocyclopropanes with 3-aryl-2-cyanoacrylate has been developed.

DBU-mediated [4 + 2] annulations of donor–acceptor cyclopropanes with 3-aryl-2-cyanoacrylates for the synthesis of fully substituted anilines