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Cu/SAPO-34 catalysts were prepared by wet impregnation and ion-exchange methods, and both the catalysts were hydrothermally treated at 750 °C in 10 vol% H2O/air for 24 h. Subsequently, the as-received and hydrothermally treated catalysts were exposed to a sulfur poisoning treatment at 350 °C in 100 ppm SO2/10 vol% H2O/air for 24 h and examined for NOxconversion. Sulfur poisoning considerably decreased the NOxconversion efficiency of the catalysts at low temperatures. In contrast, it improved the high-temperature selective catalytic reduction (SCR) activities of the as-received catalysts. The ion-exchange-prepared catalysts displayed higher sulfur tolerance than the impregnation-prepared catalysts at 150-350 °C. The electron paramagnetic resonance, X-ray photoelectron spectroscopy, energy-dispersive X-ray spectroscopy and H2-temperature-programmed reduction results showed that sulfur poisoning significantly influenced the migration of the copper species and thereby the amount of active isolated Cu2+. More dispersed CuSO4was produced on the ion-exchange-prepared catalysts than on the impregnation-prepared catalysts after sulfur poisoning. The dispersed CuSO4showed considerably higher SCR activity than the crystalline CuSO4. Both the dispersed CuSO4and remaining isolated Cu2+determined the low-temperature SCR behavior of the sulfur-poisoned catalysts. © 2017 The Royal Society of Chemistry.

Migration, reactivity, and sulfur tolerance of copper species in SAPO-34 zeolite toward NOx reduction with ammonia

Migration, reactivity, and sulfur tolerance of copper species in SAPO-34 zeolite toward NO_x reduction with ammonia