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A structurally characterized titanium complex [Ti(Phen)(OC 2 H 5 ) 2 Cl 2 ] (Phen = 1,10-phenanthroline) is reported as a homogeneous pre-catalyst for the selective oxidation of organic sulfides to sulfoxides with a stoichiometric amount H 2 O 2  in CH 3 OH at room temperature.

rsc advances

Ti(Phen)(OC2H5)2Cl2: a highly efficient pre-catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide