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MgCl 2  unexpectedly interacts with [NH 3 ] units in NH 3 BH 3 , analogous to the amine complex of Mg(NH 3 ) x Cl 2 , resulting in superior desorption.

rsc advances

The superior desorption properties of MgCl2-added ammonia borane compared to MgF2-added systems—the unexpected role of MgCl2 interacting with [NH3] units