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Our method of calculating Brown's bond valence sum clarified coordinations of N 3−  and O 2−  at each site in (Y,Ca) 6+x/3 Si 11 (N,O) 21 :Ce phosphor.

Characterization of blue-excited yellow phosphor (Y,Ca)6+x/3Si11(N,O)21:Ce by the bond valence sum model

Characterization of blue-excited yellow phosphor (Y,Ca)_6+x/3Si₁₁(N,O)₂₁:Ce by the bond valence sum model